D.S. Bethune, J.R. Lankard, et al.
The Journal of Chemical Physics
The gas phase IR spectrum of t-butyl radicals near ∼3μm has been observed by the time-resolved infrared technique known as TRISP. The transient spectrum is observed to decay with second-order kinetics, and a total rate of decay kc + kd = 1010.26 liter mole-1 sec-1 is measured. From a gas chromatograph/mass spectrometer analysis of the reaction products, it is found that kd/kc = 2.9. Thus kc = 109.6 l and kd = 10 10.13 liter mole-1 sec-1. The t-butyl radicals were created by ruby laser photolysis of monomeric (CH3) 3CNO vapor. © 1981 American Institute of Physics.
D.S. Bethune, J.R. Lankard, et al.
The Journal of Chemical Physics
P.P. Sorokin, J.R. Lankard
IEEE JQE
P.P. Sorokin, J.R. Lankard, et al.
Applied Physics Letters
Y. Kang, D.S. Bethune, et al.
SPIE ITCom 2003