The role of AsF5 in modifying the electrical properties of polyacetylene, (CH)x

Thomas C. Clarke; Roy H. Geiss; William D. Gill; Paul M. Grant; John W. Macklin; Hans Morawitz; John F. Rabolt; Dale Sayers; G.Bryan Street

doi:10.1039/C39790000332

Journal of the Chemical Society, Chemical Communications

Paper

01 Dec 1979

The role of AsF₅ in modifying the electrical properties of polyacetylene, (CH)_x

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Abstract

In contrast to previous results we present evidence that AsF5 reacts with polyacetylene to oxidize the (CH)x chains, in analogy with other acceptors, and to form AsF6- anions, which intercalate between the polyolefinic cation chains.

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