Carbon-13 CIDNP in the reversible addition of pentafluorobenzoyloxy radicals to chlorobenzene

R. Kaptein; R. Freeman; H.D.W. Hill; J. Bargon

doi:10.1039/C39730000953

Journal of the Chemical Society, Chemical Communications

Paper

01 Dec 1973

Carbon-13 CIDNP in the reversible addition of pentafluorobenzoyloxy radicals to chlorobenzene

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Abstract

13C CIDNP observed during photolysis of perfluorobenzoyl peroxide in the presence of chlorobenzene provides evidence for the reversible formation of a σ-complex of the pentafluorobenzoyloxy-radical with chlorobenzene, predominantly via attack at the ortho and para positions.

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