A new mechanism for photodecomposition and acid formation from triphenylsulphonium salts

John L. Dektar; Nigel P. Hacker

doi:10.1039/C39870001591

Journal of the Chemical Society, Chemical Communications

Paper

01 Dec 1987

A new mechanism for photodecomposition and acid formation from triphenylsulphonium salts

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Abstract

A new photodecomposition pathway for triphenylsulphonium salts yields phenylthiobiphenyls by a cage fragmentation-recombination process as major products, in addition to diphenyl sulphide; a new mechanism for acid formation is described.

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